Catecholase biomimetic copper(II) complex immobilization via Schiff's base formation onto the cross-linked polymers prepared by drop-casting

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dc.contributor.author Sýs, Milan
dc.contributor.author Bártová, Michaela
dc.contributor.author Hartmanová, Aneta
dc.contributor.author Mikysek, Tomáš
dc.contributor.editor Adam, Martin
dc.date.accessioned 2022-09-21T11:16:35Z
dc.date.available 2022-09-21T11:16:35Z
dc.date.issued 2022
dc.identifier.isbn 978-80-7560-428-6
dc.identifier.issn 1211-5541
dc.identifier.uri https://hdl.handle.net/10195/80398
dc.description.abstract In this article, a universal protocol is introduced dealing with covalent immobilization of catecholase biomimetic copper(II) complexes with free carbonyl group onto the primary amine-based polymeric substrates (chitosan and collagen, type II) cross-linked with glutar-aldehyde; both being enabled via Schiff's base formation. As a representative of biomimetic catalysts, [Cu2Ac2O(L)ClO4] consisting of a 2,6-bis(4-methyl piperazin-1-ylmethyl)- 4-formyl-phenoxy ligand (L) was selected. The resulting functionalized polymers formed at the surface of a screen-printed carbon electrode were characterized using scanning electron microscopy with energy dispersive X-ray analysis. As a result, the procedure presented herein could find use in the development of artificial biosensors. en
dc.format p. 17-25
dc.language.iso eng
dc.publisher University of Pardubice en
dc.relation.ispartof Scientific papers of the University of Pardubice. Series A, Faculty of Chemical Technology. 28/2022 en
dc.rights open access en
dc.subject biomimetic enzymes en
dc.subject functionalized polymers en
dc.subject Schiff's base formation en
dc.subject drop-casting en
dc.subject scanning electron microscopy en
dc.title Catecholase biomimetic copper(II) complex immobilization via Schiff's base formation onto the cross-linked polymers prepared by drop-casting en
dc.type article en
dc.peerreviewed yes en
dc.publicationstatus published en


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