Zobrazit minimální záznam
dc.contributor.author |
Sýs, Milan
|
|
dc.contributor.author |
Bártová, Michaela
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|
dc.contributor.author |
Hartmanová, Aneta
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|
dc.contributor.author |
Mikysek, Tomáš
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|
dc.contributor.editor |
Adam, Martin |
|
dc.date.accessioned |
2022-09-21T11:16:35Z |
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dc.date.available |
2022-09-21T11:16:35Z |
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dc.date.issued |
2022 |
|
dc.identifier.isbn |
978-80-7560-428-6 |
|
dc.identifier.issn |
1211-5541 |
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dc.identifier.uri |
https://hdl.handle.net/10195/80398 |
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dc.description.abstract |
In this article, a universal protocol is introduced dealing with covalent immobilization of
catecholase biomimetic copper(II) complexes with free carbonyl group onto the primary
amine-based polymeric substrates (chitosan and collagen, type II) cross-linked with
glutar-aldehyde; both being enabled via Schiff's base formation. As a representative of
biomimetic catalysts, [Cu2Ac2O(L)ClO4] consisting of a 2,6-bis(4-methyl piperazin-1-ylmethyl)-
4-formyl-phenoxy ligand (L) was selected. The resulting functionalized polymers
formed at the surface of a screen-printed carbon electrode were characterized using
scanning electron microscopy with energy dispersive X-ray analysis. As a result, the
procedure presented herein could find use in the development of artificial biosensors. |
en |
dc.format |
p. 17-25 |
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dc.language.iso |
eng |
|
dc.publisher |
University of Pardubice |
en |
dc.relation.ispartof |
Scientific papers of the University of Pardubice. Series A, Faculty of Chemical Technology. 28/2022 |
en |
dc.rights |
open access |
en |
dc.subject |
biomimetic enzymes |
en |
dc.subject |
functionalized polymers |
en |
dc.subject |
Schiff's base formation |
en |
dc.subject |
drop-casting |
en |
dc.subject |
scanning electron microscopy |
en |
dc.title |
Catecholase biomimetic copper(II) complex immobilization via Schiff's base formation onto the cross-linked polymers prepared by drop-casting |
en |
dc.type |
article |
en |
dc.peerreviewed |
yes |
en |
dc.publicationstatus |
published |
en |
dc.identifier.obd |
39887476 |
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