The glass-transition temperature and both the topological and chemical thresholds in chalcogenide glasses

dc.contributor.author	Tichý, Ladislav
dc.contributor.author	Tichá, Helena
dc.date.accessioned	2021-02-22T12:12:09Z
dc.date.available	2021-02-22T12:12:09Z
dc.date.issued	1996
dc.identifier	Univerzitní knihovna (studovna)	cze
dc.identifier.issn	1211-5541
dc.identifier.uri	https://hdl.handle.net/10195/76837
dc.description.abstract	The problem of the glass-transition temperature (Tg) is discussed using the idea of the topological and chemical threshold in chalcogenide glasses. Within a simple covalent bond approach it is shown that the short range bonding arrangement mainly determines the Tg values in chalcogenide glasses. Good correlation between Tg and the overall mean bond energy, (〈E〉), of a covalent network of a glass was found for 186 binary and ternary chalcogenide glasses. This correlation satisfies the Arrhenius relation for viscosity, where the apparent activation energy of viscosity is empirically related to the overall mean bond energy.	cze
dc.format	p. 267-290
dc.language.iso	en	cze
dc.publisher	Univerzita Pardubice	cze
dc.relation.ispartof	Scientific papers of the University of Pardubice. Series A, Faculty of Chemical technology. 2(1996)	eng
dc.rights	open access	eng
dc.title	The glass-transition temperature and both the topological and chemical thresholds in chalcogenide glasses	cze
dc.type	Article	cze
dc.identifier.signature	47333-2
dc.peerreviewed	yes	eng
dc.publicationstatus	published	eng