Spectral, electrochemical and calculated properties of quadrupolar chromophores based on tetrafluorobenzene
ČlánekOtevřený přístuppeer-reviewedpublishedSoubory
Datum publikování
2014
Vedoucí práce
Oponent
Název časopisu
Název svazku
Vydavatel
University of Pardubice
Abstrakt
Absorption/emission and electrochemical properties of four new quadrupolar
push-pull-push molecules with central tetrafluorobenzene acceptor and two
peripheral N,N-dihexylamino and O-hexyloxy donor groups were investigated.
Experimental data were completed with quantum-chemical calculations. The
extent of the intramolecular charge-transfer and nonlinear optical properties were
elucidated in terms of structure-property relationships. The electronic nature of
the appended donor group, length, planarity and composition of the B-linker
(combination of 1,4-phenylene, 2,5-thienylene and acetylenic subunits) are the
most important factors affecting the linear as well as nonlinear optical properties.
Rozsah stran
p. 221–228
ISSN
1211-5541
Trvalý odkaz na tento záznam
Projekt
Zdrojový dokument
Scientific papers of the University of Pardubice. Series A, Faculty of Chemical Technology. 20/2014
Vydavatelská verze
Přístup k e-verzi
open access
Název akce
ISBN
978-80-7395-814-5