Carbon paste electrode modified with thiourea-functionalized resin for determination of lead
ČlánekOtevřený přístuppeer-reviewedpublisher's versionDatum publikování
2009
Vedoucí práce
Oponent
Název časopisu
Název svazku
Vydavatel
University of Pardubice
Abstrakt
In this contribution, a carbon paste electrode modified with thiourea-functionalised resin is described in terms of its electroanalytical characterisation and applicability to the determination of Pb2+ ions. Commercial macroporous resin, QuadraPure(TM)TU, added to the carbon paste mixture in an amount of 30% (v/v), contains thiourea residual groups being able of effectively complexing the Pb2+ ions. When using the SWV mode in combination with open-circuit accumulation, intermediate electrolytic reduction, and subsequent anodic stripping step, the resultant signal for lead could be calibrated within a very wide concentration range of 5–25 000 μg L−1 Pb2+, with a limit of detection (3 sigma) of about 1 μg L−1, and without serious interferences from other heavy metal ions as confirmed in special studies. Practical usefulness of the method has been tested on selected water samples and the respective results verified by means of recovery rates, certified reference material, and ICP-MS reference determinations.
Rozsah stran
p. 5–27
ISSN
1211-5541
Trvalý odkaz na tento záznam
Projekt
Zdrojový dokument
Scientific papers of the University of Pardubice. Series A, Faculty of Chemical Technology. 15/2009
Vydavatelská verze
Přístup k e-verzi
open access
Název akce
ISBN
978-80-7395-239-6