Addition of in-situ reduced amidinato-methylaluminium chloride to acetylenes

Show simple item record Chlupatý, Tomáš Turek, J. De Proft, F. Růžičková, Zdeňka Růžička, Aleš 2016-03-03T07:37:02Z 2016-03-03T07:37:02Z 2015-09-10
dc.identifier.issn 1477-9226
dc.description.abstract Two ethylene-bridged methylaluminium amidinates and one aluminium amidinate containing three terminal trimethylstannyl-ethynyl groups interconnected by π-coordinated potassium ions were prepared in situ. The re-oxidation of the ethylene-bridged compound by iodine followed by further reduction using the same activation procedure demonstrated the versatility of the approach. The reactivity of an ethylene-bridged methylaluminum amidinate towards HCl was examined to demonstrate the building block concept. DFT calculations were performed to gain insight into the mechanism of the in situ activation of diphenylacetylene. eng
dc.format p. 17462-17466 eng
dc.language.iso eng
dc.publisher Royal Society of Chemistry eng
dc.relation.ispartof Dalton Transactions. 2015, vol. 44 eng
dc.rights open access eng
dc.rights Attribution-NonCommercial 3.0 Czech Republic *
dc.rights.uri *
dc.title Addition of in-situ reduced amidinato-methylaluminium chloride to acetylenes eng
dc.type Article eng
dc.peerreviewed yes eng
dc.publicationstatus published eng
dc.identifier.doi 10.1039/C5DT03128A
dc.identifier.wos WOS:000362362500004
dc.identifier.scopus 2-s2.0-84943564749

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