Addition of in-situ reduced amidinato-methylaluminium chloride to acetylenes
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2015-09-10
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Royal Society of Chemistry
Abstrakt
Two ethylene-bridged methylaluminium amidinates and one aluminium amidinate containing three terminal trimethylstannyl-ethynyl groups interconnected by π-coordinated potassium ions were prepared in situ. The re-oxidation of the ethylene-bridged compound by iodine followed by further reduction using the same activation procedure demonstrated the versatility of the approach. The reactivity of an ethylene-bridged methylaluminum amidinate towards HCl was examined to demonstrate the building block concept. DFT calculations were performed to gain insight into the mechanism of the in situ activation of diphenylacetylene.
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p. 17462-17466
ISSN
1477-9226
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Dalton Transactions. 2015, vol. 44
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http://pubs.rsc.org/en/content/articlelanding/2015/dt/c5dt03128a?iscitedby=True#!divAbstract
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open access
Attribution-NonCommercial 3.0 Czech Republic
Attribution-NonCommercial 3.0 Czech Republic
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