The essentials of a remarkable carbon skeleton rearrangement of aldoses catalyzed with molybdic acid and known as the Bílik reaction are introduced. The extension of the reaction to a mutual interconversion of 2-ketoses and 2-C-(hydroxymethyl)-aldoses is also described. Finally, the molybdic acid catalysis is briefly compared with other known systems catalyzing similar transformations.
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p. 121-127
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eng
dc.publisher
Univerzita Pardubice
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dc.relation.ispartof
Scientific papers of the University of Pardubice. Series A, Faculty of Chemical technology. 5 (1999)
eng
dc.rights
open access
eng
dc.subject
organická chemie
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dc.subject
organické reakce
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dc.subject
Bílkova reakce
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dc.subject
katalýza
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dc.subject
přesmyky
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dc.title
Catalyzed carbon skeleton rearrangement of basic carbohydrates