Publikace: Modulation of (non)linear optical properties in tripodal molecules by variation of the peripheral cyano acceptor moieties and the π-spacer
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Cvejn, Daniel
Michail, Eugene
Polyzos, Ioannis
Almonasy, Numan
Pytela, Oldřich
Klikar, Milan
Mikysek, Tomáš
Giannetas, Vassilis G.
Fakis, Mihalis
Bureš, Filip
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Royal Society of Chemistry
Abstrakt
A series of twelve tripodal push-pull molecules with a central triphenylamine donor and peripheral cyano substituted acceptors has been prepared. These molecules possess systematically altered π-linkers as well as cyano acceptors. Based on the experimental properties measured by differential scanning calorimetry, electrochemistry, one and two photon absorption/emission spectroscopy, supported by the DFT calculations, thorough structure–property relationships were elucidated.