Publikace: A diamantane-4,9-dicarboxylate based UiO-66 analogue: challenging larger hydrocarbon cage platforms
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Gvilava, Vasily
Vieten, Maximilian
Oestreich, Robert
Woschko, Dennis
Steinert, Moritz
Boldog, Ishtvan
Bulánek, Roman
Fokina, Natalie A
Schreiner, Peter R
Janiak, Christoph
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ROYAL SOC CHEMISTRY
Abstrakt
The first use of a bulky barrel-shaped ligand is demonstrated in HHUD-3, with accessible porosity only feasible for a defect structure. With 35%+ missing linker defects and S-BET = 890 m(2)g(-1) (N-2), HHUD-3 features higher CH4 but lower CO2 and H-2 adsorption than UiO-66.
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Klíčová slova
metal-organic framework, chemistry, zr, diamondoids, hydrogen, defects, design, carbon, acid, Diamantan, UiO-66 analog, vodík, uhlík, kyselina, Me-organická síť