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Pd@CN-COF: a pool for palladium(0)-catalyzed reactions

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dc.contributor.authorHoráková, Marcela
dc.contributor.authorKlikar, Milan
dc.contributor.authorHalamek, Jakub
dc.contributor.authorBulánek, Roman
dc.contributor.authorRodriguez-Pereira, Jhonatan
dc.contributor.authorČičmancová, Veronika
dc.contributor.authorPodlesný, Jan
dc.contributor.authorKolíbalová, Eva
dc.contributor.authorMichalička, Jan
dc.contributor.authorBartáček, Jan
dc.contributor.authorPařík, Patrik
dc.contributor.authorMacak, Jan M.
dc.contributor.authorBureš, Filip
dc.date.accessioned2026-04-23T08:51:43Z
dc.date.issued2026
dc.description.abstractA new cyano-substituted olefin-linked COF was synthesized and utilized as a support for palladium nanoparticles. The resulting Pd@CN-COF was demonstrated as a versatile heterogeneous catalyst in crosscoupling reactions, cyanation, and allylic substitution with the productivity exceeding the commercial homogeneous precatalyst [Pd(PPh3)4]. The catalytic activity of Pd@CN-COF was further evaluated in synthetically valuable transformations towards industrially, agrochemically, and pharmacologically relevant products.eng
dc.format8 p.eng
dc.identifier.doi10.1039/d5qm00889a
dc.identifier.issn2052-1537
dc.identifier.urihttps://hdl.handle.net/10195/87621
dc.language.isoeng
dc.peerreviewedyeseng
dc.project.IDMŠMT/OP JAK/02_23_021/CZ/Inovativní materiály vhodné pro aplikace s vysokou přidanou hodnotou/INMAcze
dc.publicationstatuspublishedeng
dc.publisherRoyal Society of Chemistry (RSC)
dc.relationhttps://doi.org/10.6084/m9.figshare.30691823
dc.relation.ispartofMaterials Chemistry Frontiers. 2026
dc.relation.publisherversionhttps://pubs.rsc.org/en/content/articlelanding/2026/qm/d5qm00889a
dc.rightsopen accesseng
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/
dc.subjectcatalysiseng
dc.subjectcobalt compoundseng
dc.subjectcrosslinkingeng
dc.subjectpalladiumeng
dc.subjectpalladium compoundseng
dc.subjectsubstitutions reactionseng
dc.subjectsynthesiseng
dc.titlePd@CN-COF: a pool for palladium(0)-catalyzed reactionseng
dc.typeArticle

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