dc.contributor.author |
Mlekodaj, Kinga
|
|
dc.contributor.author |
Lemishka, Mariia
|
|
dc.contributor.author |
Sklenak, Stepan
|
|
dc.contributor.author |
Dedecek, Jiri
|
|
dc.contributor.author |
Tabor, Edyta
|
|
dc.date.accessioned |
2022-06-03T12:09:10Z |
|
dc.date.available |
2022-06-03T12:09:10Z |
|
dc.date.issued |
2021 |
|
dc.identifier.issn |
1359-7345 |
|
dc.identifier.uri |
https://hdl.handle.net/10195/79021 |
|
dc.description.abstract |
Here we demonstrate for the first time the splitting of dioxygen at RT over distant binuclear transition metal (M = Ni, Mn, and Co) centers stabilized in ferrierite zeolite. Cleaved dioxygen directly oxidized methane to methanol, which can be released without the aid of an effluent to the gas phase at RT. |
eng |
dc.format |
p. 3472-3475 |
eng |
dc.language.iso |
eng |
|
dc.publisher |
Royal Society of Chemistry |
eng |
dc.relation.ispartof |
Chemical Communications, volume 57, issue: 28 |
eng |
dc.rights |
pouze v rámci univerzity |
cze |
dc.subject |
zeolites |
eng |
dc.subject |
oxidation of methane |
eng |
dc.subject |
transition metals |
eng |
dc.subject |
dioxygens |
eng |
dc.subject |
room temperature |
eng |
dc.subject |
zeolity |
cze |
dc.subject |
oxidace metanu |
cze |
dc.subject |
přechodové kovy |
cze |
dc.subject |
kyslík |
cze |
dc.subject |
pokojová teplota |
cze |
dc.title |
Dioxygen splitting at room temperature over distant binuclear transition metal centers in zeolites for direct oxidation of methane to methanol |
eng |
dc.title.alternative |
Štěpení kyslíku při pokojové teplotě na vzdálených dvouatomových centrech přechodových kovů v zeolitech pro přímou oxidaci metanu na metanol |
cze |
dc.type |
article |
eng |
dc.description.abstract-translated |
Zde demonstrujeme první štěpení kyslíku při pokojové teplotě na vzdálených centrech přechodových kovů v zeolitech typu FER. Aktivovaný kyslík poté oxidoval metan na metanol při pokojové teplotě. |
cze |
dc.peerreviewed |
yes |
eng |
dc.publicationstatus |
published version |
eng |
dc.identifier.doi |
10.1039/d1cc00909e |
|
dc.relation.publisherversion |
https://pubs.rsc.org/en/content/articlelanding/2021/CC/D1CC00909E |
|
dc.identifier.wos |
000637108400007 |
|
dc.identifier.scopus |
2-s2.0-85103733152 |
|
dc.identifier.obd |
39886580 |
|