Zobrazit minimální záznam
dc.contributor.author |
Mrózek, Ondřej
|
cze |
dc.contributor.author |
Vinklárek, Jaromír
|
cze |
dc.contributor.author |
Dostál, Libor
|
cze |
dc.contributor.author |
Růžičková, Zdeňka
|
cze |
dc.contributor.author |
Honzíček, Jan
|
cze |
dc.date.accessioned |
2019-05-22T08:24:51Z |
|
dc.date.available |
2019-05-22T08:24:51Z |
|
dc.date.issued |
2018 |
eng |
dc.identifier.issn |
0277-5387 |
eng |
dc.identifier.uri |
https://hdl.handle.net/10195/72676 |
|
dc.description.abstract |
Organometallic molybdenum compounds bearing poly[(methylthio)methyllborates, [(eta(3)-C3H5)Mo (CO)(2)(kappa(3)-PhTt)] and [Bu4N][{((eta(3)-C3H5)Mo(CO)(2)Cl)(2)(kappa(2):kappa(2)-RTt)], where PhTt = phenyltris[(methylthio) methyllborate and RTt = tetralds[(methylthio)methyl]borate, have been obtained by ligand exchange reaction from [(eta(3)-C3H5)Mo(CO)(2)(NCMe)(2)Cl] and appropriate borate. The PhTt ligand provides tridentate face-capping coordination to the central metal while the RTt acts as a bridging ligand and connects two [(eta(3)-C3H5)Mo(CO)(2)Cl] monomeric units by unusual kappa(2):kappa(2)-coordination mode. Both compounds were fully characterized by spectroscopic methods and X-ray crystallography. |
eng |
dc.format |
p. 35-39 |
eng |
dc.language.iso |
eng |
eng |
dc.publisher |
Elsevier Science |
eng |
dc.relation.ispartof |
Polyhedron, volume 150, issue: August |
eng |
dc.rights |
embargoed access |
eng |
dc.subject |
Molybdenum |
eng |
dc.subject |
Scorpionates |
eng |
dc.subject |
NMR spectroscopy |
eng |
dc.subject |
X-ray diffraction |
eng |
dc.subject |
Molybden |
cze |
dc.subject |
škorpionáty |
cze |
dc.subject |
NMR spektroskopie |
cze |
dc.subject |
RTG difrakce |
cze |
dc.title |
Molybdenum complexes of poly[(methylthio)methyl]borates |
eng |
dc.title.alternative |
Komplexy molybdenu s polymethylthiomethylboraty. |
cze |
dc.type |
article |
eng |
dc.description.abstract-translated |
Organokovové sloučeniny nesoucí polymethylthioboraty byly připraveny a charakterizovány dostupnými spektroskopickými metodami. Struktura dvou produktů byla stanovena rentgenovou difrakční analýzou. |
cze |
dc.peerreviewed |
yes |
eng |
dc.publicationstatus |
postprint |
eng |
dc.identifier.doi |
10.1016/j.poly.2018.04.036 |
eng |
dc.identifier.wos |
000437053900006 |
eng |
dc.identifier.scopus |
2-s2.0-85047154314 |
|
dc.identifier.obd |
39881474 |
eng |
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