| dc.contributor.author |
Honzíček, Jan
|
cze |
| dc.contributor.author |
Růžičková, Zdeňka
|
cze |
| dc.contributor.author |
Vinklárek, Jaromír
|
cze |
| dc.date.accessioned |
2017-05-11T11:11:39Z |
|
| dc.date.available |
2017-05-11T11:11:39Z |
|
| dc.date.issued |
2016 |
eng |
| dc.identifier.issn |
0020-1693 |
eng |
| dc.identifier.uri |
http://hdl.handle.net/10195/67605 |
|
| dc.description.abstract |
A key hydrolysis product of vanadocene dichloride was isolated and structurally characterized. The oligomeric character of the species precludes its detection by classical EPR spectroscopic tools. A detailed study of the with high purity reagents disproves appearance of Cp2V(OH)2, which was postulated previously based on mechanistic approach. |
eng |
| dc.format |
p. 39-41 |
eng |
| dc.language.iso |
eng |
eng |
| dc.relation.ispartof |
Inorganica Chimica Acta, volume 453, issue: November |
eng |
| dc.rights |
embargoed access |
eng |
| dc.subject |
vanadium |
eng |
| dc.subject |
hydrolysis |
eng |
| dc.subject |
vanad |
cze |
| dc.subject |
hydrolýza |
cze |
| dc.title |
Hydrolysis of vanadocene dichloride: A revisit |
eng |
| dc.title.alternative |
Hydrolýza vanadocen dichloridu |
cze |
| dc.type |
article |
eng |
| dc.description.abstract-translated |
Klíčový produkt hydrolýzy vanadocendichloridu byl izolován a strukturně charakterizován. Oligomerní charakter této částice neumožňuje její detekci pomocí EPR spektroskopie. Podrobná studie vyloučila možnost vzniku dríve postulovaného komplexu Cp2V(OH)2. |
cze |
| dc.peerreviewed |
yes |
eng |
| dc.publicationstatus |
postprint |
eng |
| dc.identifier.doi |
10.1016/j.ica.2016.07.054 |
|
| dc.identifier.wos |
000387625500006 |
|
| dc.identifier.scopus |
2-s2.0-84980401130 |
|
| dc.identifier.obd |
39877400 |
eng |
