Zobrazit minimální záznam
dc.contributor.author |
Zhao, Yu |
|
dc.contributor.author |
Zhang, Chenhao |
|
dc.contributor.author |
Foo Chin, Kek |
|
dc.contributor.author |
Pytela, Oldřich |
|
dc.contributor.author |
Wei, Guo |
|
dc.contributor.author |
Liu, Hongjun |
|
dc.contributor.author |
Bureš, Filip |
|
dc.contributor.author |
Zhiyong, Jiang |
|
dc.date.accessioned |
2014-12-16T15:00:17Z |
|
dc.date.available |
2014-12-16T15:00:17Z |
|
dc.date.issued |
2014 |
|
dc.identifier.issn |
2046-2069 |
|
dc.identifier.uri |
http://hdl.handle.net/10195/58484 |
|
dc.description.abstract |
Here, we report dicyanopyrazine (DPZ)-derived push–pull chromophores, easily prepared and tunable organic compounds, as new kinds of photoredox catalysts. In particular, the DPZ derivative H, containing 2-methoxythienyl as electron-donating moiety, exhibits a broad absorption of visible light with an absorption edge up to 500 nm and excellent redox properties, and has been demonstrated as a desirably active and efficient photoredox catalyst in four challenging kinds of photoredox reactions. The amount of catalyst in most reactions is less than 0.1 mol% and even 0.01 mol%, representing the lowest catalyst loading in the current photoredox organocatalysis. |
eng |
dc.format |
p. 30062-30067 |
eng |
dc.language.iso |
eng |
|
dc.publisher |
Royal Society of Chemistry |
cze |
dc.relation.ispartof |
RSC Advances. 2014, issue 57 |
eng |
dc.rights |
open access |
eng |
dc.title |
Dicyanopyrazine-derived push–pull chromophores for highly efficient photoredox catalysis |
cze |
dc.type |
Article |
cze |
dc.peerreviewed |
yes |
eng |
dc.publicationstatus |
published |
eng |
dc.identifier.doi |
10.1039/C4RA05525J |
|
dc.rights.licence |
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence http://creativecommons.org/licenses/by-nc/3.0/ |
eng |
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