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Publikace:
Activity and selectivity of Mg-Fe mixed oxides in the aldol condensation of furfural

Článekopen accesspeer-reviewedpublished version
dc.contributor.authorKocík, Jaroslavcze
dc.contributor.authorKikhtyanin, Olegcze
dc.contributor.authorTomášová, Adélacze
dc.contributor.authorSmoláková, Luciecze
dc.contributor.authorHájek, Martincze
dc.contributor.authorČapek, Liborcze
dc.date.accessioned2017-05-11T11:20:19Z
dc.date.available2017-05-11T11:20:19Z
dc.date.issued2016eng
dc.description.abstractThe aim of this work has been to compare the activity and selectivity of Mg-Fe mixed oxides in the aldol condensation of furfural with that of previously studied Mg-Al mixed oxides. Mg-Fe mixed oxides were prepared by thermal pre-treatment of hydrotalcites with a Mg/Fe molar ratio from 1.1 to 7.6. Structural and textural properties of Mg-Fe mixed oxides were analysed by using of XRD and N2-adsorption. It was found that Mg-Fe mixed oxides exhibited lower conversion of furfural in contrast to the Mg-Al mixed oxides, but being more selective to 4-(2-furyl)-3-buten-2-one (FAc). The difference in the conversion of furfural was relatively low among the Mg-Fe mixed oxides with the Mg/Fe molar ratio in the range of 1.1-5.5.eng
dc.description.abstract-translatedCílem práce bylo porovnat aktivitu a selektivitu směsných oxidů Mg-Fe v aldolové kondenzaci furfuralu s dříve zkoumanýmni směsnými oxidy Mg-Al.cze
dc.formatp. 81-90eng
dc.identifier.issn1211-5541eng
dc.identifier.obd39878183eng
dc.identifier.urihttps://hdl.handle.net/10195/67712
dc.language.isoengeng
dc.peerreviewedyeseng
dc.project.IDGA15-21817S/Analýza vztahu mezi strukturou/basicitou Mg/Al, Ca/Al a Zn/Al směsných oxidů a jejich aktivitou v aldol kondenzaci a transesterifikacieng
dc.publicationstatuspublished versioneng
dc.relation.ispartofScientific Papers of the University of Pardubice, Series A, Faculty of Chemical Technology, volume 22, issue: květen 2016eng
dc.rightsopen accesseng
dc.subjectcatalytic activityeng
dc.subjectMg-Feeng
dc.subjectmixed oxideseng
dc.subjectaldol condensationeng
dc.subjectfurfuraleng
dc.subjectkatalytická aktivitacze
dc.subjectMg-Fecze
dc.subjectsměsné oxidycze
dc.subjectaldolová kondenzacecze
dc.subjectfurfuralcze
dc.titleActivity and selectivity of Mg-Fe mixed oxides in the aldol condensation of furfuraleng
dc.title.alternativeAktivita a selektivita směsných oxidů Mg-Fe v aldolové kondenzaci furfuralucze
dc.typeArticleeng
dspace.entity.typePublication

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