Syntéza a vlastnosti modelových push-pull molekul na bázi indan-1,3-dionu

Abstract

This work deals with the design, synthesis, characterization and physico-chemical properties of indane-1,3-dione based push-pull chromophores. All target chromophores were prepared via. knoevenagel condensation followed by Suzuki-Miyaura or Sonogashira cross-coupling reaction. Their structure and properties were further investigated by X-ray analysis, electrochemistry, UV/Vis absorption spectroscopy, differerential scanning calorimetry, electric-fild-induced second-harmonic generation (EFISHG) studies and DFT calkulations. Structure-property relationships were elucidated.