Copper-Catalyzed Reactions of Aryl Halides with N-Nucleophiles and Their Possible Application for Degradation of Halogenated Aromatic Contaminants
ČlánekOtevřený přístuppeer-reviewedpublishedDatum publikování
2022
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Weidlich, Tomáš
Špryncová, Martina
Čegan, Alexander
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MDPI
Abstrakt
This review summarizes recent applications of copper or copper-based compounds as a nonprecious metal catalyst in N-nucleophiles-based dehalogenation (DH) reactions of halogenated aromatic compounds (Ar-Xs). Cu-catalyzed DH enables the production of corresponding nonhalogenated aromatic products (Ar-Nu), which are much more biodegradable and can be mineralized during aerobic wastewater treatment or which are principally further applicable. Based on available knowledge, the developed Cu-based DH methods enable the utilization of amines for effective cleavage of aryl-halogen bonds in organic solvents or even in an aqueous solution.
Rozsah stran
p. 911
ISSN
2073-4344
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Zdrojový dokument
Catalysts, volume 12, issue: 8
Vydavatelská verze
https://www.mdpi.com/2073-4344/12/8/911
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open access
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amine, amination, arylation, halogenated aromatic compounds, aryl halide, dehalogenation, C-N cross-coupling, amin, aminace, arylace, halogenované aromatické sloučeniny, arylhalogenid, dehalogenace, C-N křížová vazba
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Except where otherwised noted, this item's license is described as open access