dc.contributor.author |
Křižan, Martin
|
cze |
dc.contributor.author |
Vinklárek, Jaromír
|
cze |
dc.contributor.author |
Erben, Milan
|
cze |
dc.contributor.author |
Císařová, Ivana
|
cze |
dc.contributor.author |
Honzíček, Jan
|
cze |
dc.date.accessioned |
2018-02-27T03:41:09Z |
|
dc.date.available |
2018-02-27T03:41:09Z |
|
dc.date.issued |
2017 |
eng |
dc.identifier.issn |
0300-9440 |
eng |
dc.identifier.uri |
https://hdl.handle.net/10195/70289 |
|
dc.description.abstract |
A new iron(II) bispidine complex with increased solubility in various organic solvents has been prepared and characterized by the spectroscopic methods and the X-ray crystallography. In-depth infrared study together with mechanical tests demonstrated the excellent catalytic performance of the iron compound in autoxidation process and established it as the potent drier suitable for solvent-borne alkyd binders. This study further reports the 2D-correlation analysis of the time-resolved infrared spectra, which was used for the first time for detailed analysis of the autoxidation process mechanism. |
eng |
dc.format |
p. 361-370 |
eng |
dc.language.iso |
eng |
eng |
dc.publisher |
Elsevier Science BV |
eng |
dc.relation.ispartof |
Progress in Organic Coatings, volume 111, issue: 1 |
eng |
dc.rights |
embargoed access |
eng |
dc.subject |
Bispidine |
eng |
dc.subject |
Alkyd resin |
eng |
dc.subject |
Autoxidation |
eng |
dc.subject |
Infrared spectroscopy |
eng |
dc.subject |
2D correlation |
eng |
dc.subject |
bispidin |
cze |
dc.subject |
alkyd |
cze |
dc.subject |
autooxicace |
cze |
dc.subject |
infračervená spektroskopie |
cze |
dc.title |
Autoxidation of alkyd resins catalyzed by iron(II) bispidine complex: Drying performance and in-depth infrared study |
eng |
dc.title.alternative |
Autooxidace alkydových pryskyřic katalyzovaná železnatým komplexem bispidinu: zasychýní a podrobná studie mechanismu infračervenou spektroskopií |
cze |
dc.type |
article |
eng |
dc.description.abstract-translated |
Byl připraven nový železnatý komplex bispidunu se zvýšenou rozpustností v různých organických rozpouštědlech. Tato sloučenina charakterizována spektroskopickými metodami a RTG-difrakční analýzou. Podrobná studie prokázala vynikající katalytickou aktivitu tohoto komplexu. V této studii byla poprvé použita 2D-korelační analýza infračervených spekter pro analýzu mechanismu autooxidace. |
cze |
dc.peerreviewed |
yes |
eng |
dc.publicationstatus |
postprint |
eng |
dc.identifier.doi |
10.1016/j.porgcoat.2017.05.015 |
eng |
dc.identifier.wos |
000407184600037 |
eng |
dc.identifier.scopus |
2-s2.0-85021211979 |
|
dc.identifier.obd |
39879338 |
eng |